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Oxidative Dehomologation of Aldehydes with Oxygen as a Terminal Oxidant
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unpublished
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A mild, efficient protocol for oxidative cleavage of C-C bond in aldehydes has been developed that employs alkali metal hydrides as reagents and oxygen from air as a terminal oxidant. The method is applicable to a broad substrate range. Scheme 1. Strategies for oxidative cleavage of C-C bond in aldehydes.
doi:10.1021/acs.orglett.7b03512.s001
fatcat:6ipojtm2fvgujf7zat2p45vmrm