Hydrothermal Synthesis of Ce-doped BaZrO3 Fine Particles and Their Three-way Catalytic Performance for Exhaust Gas Purification
セリウムドープジルコン酸バリウム微粒子の水熱合成と三元触媒担体としての排ガス浄化特性評価

Yuki SEINO, Kiyoshi KANIE, Atsushi MURAMATSU
2017 Journal of MMIJ  
キーワード: 三元触媒,自動車排ガス浄化,ジルコン酸バリウム,セリウム ドープ Cerium-doped barium zirconate (Ce-doped BaZrO 3 ) fine particles with high crystallinity was prepared by a hydrothermal reaction using barium hydroxide, CeCl 3 , and a Zr-triethanolamine complex. Characterization of the Ce-doped BaZrO 3 particles revealed that utilization of the water-stable Zr-triethanolamine complex was an efficient way to introduce cerium ions into the BaZrO 3 perovskite crystal structure. The three-way catalytic activity of the
more » ... d BaZrO 3 for an exhaust gas conversion reaction was investigated under a stoichiometric condition (CO 0.5%, C 3 H 6 400 ppm, NO 500 ppm, O 2 0.49%, H 2 0.17%, CO 2 14%, H 2 O 10% in N 2 ). The Ce-doped BaZrO 3 exhibited a remarkable low temperature NO x cleaning performance when the Ce-doped BaZrO 3 was applied as an alternative for an Al 2 O 3 support.
doi:10.2473/journalofmmij.133.116 fatcat:ok4qrwdy7jg37dmqfu4vyrlw2i