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C–ON bond homolysis of alkoxyamines triggered by paramagnetic copper(ii) salts
Inorganic Chemistry Frontiers
Pyridine-based alkoxyamines were used as ligands for Cu(hfac)2 to prepare the first metallic complexes of alkoxyamines. Structures of complexes were determined by X-ray analysis and a 21-fold increase in the C–ON bond homolysis was observed.doi:10.1039/c6qi00277c fatcat:eodvsddub5gn7lm3ayxu43svau