C–ON bond homolysis of alkoxyamines triggered by paramagnetic copper(ii) salts

Gérard Audran, Elena Bagryanskaya, Irina Bagryanskaya, Paul Brémond, Mariya Edeleva, Sylvain R. A. Marque, Dmitriy Parkhomenko, Evgeny Tretyakov, Svetlana Zhivetyeva
2016 Inorganic Chemistry Frontiers  
Pyridine-based alkoxyamines were used as ligands for Cu(hfac)2 to prepare the first metallic complexes of alkoxyamines. Structures of complexes were determined by X-ray analysis and a 21-fold increase in the C–ON bond homolysis was observed.
doi:10.1039/c6qi00277c fatcat:eodvsddub5gn7lm3ayxu43svau