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Supplementary Information (ESI) available: Copies of 1 H and 13 C NMR spectra for all reported compounds, HPLC chromatograms and details for the determination of absolute configuration of selected examples. Crystal data file for compound ent-2b (CCDC 953178) is also provided. ABSTRACT: The reaction of a readily obtained chiral branched homoprenylamonium salt with a range of aldehydes, including aliphatic substrates, affords the corresponding linear isomers in good yields and enantioselectivities.doi:10.1039/c3ob41804a pmid:24084848 fatcat:3xto4bh4obgsxhftbg2t6dqzwy