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A s y m m e t r i c B r ø n s t e d A c i d C a t a l y z e d T r a n s f e r H y d r o g e n a t i o n s Abstract: Asymmetric hydrogenations are of great importance in the synthesis of optically active amines. This account highlights the development of the first metal-free transfer hydrogenation that is both highly enantioselective and inspired by nature's dehydrogenase. Further focus is given to the extension of this bioinspired process to provide a variety of valuable, biologically activedoi:10.1055/s-0029-1219528 fatcat:kgl4zoidjneqvkp3ejptta7adi