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Isolation of an unusual [Cu6] nanocluster through sequential addition of copper(i) to a polynucleating ligand
2017
Dalton Transactions
Preserved Fulltext
Addition of 2 equiv. of CuI to a [Cu]4 multimetallic complex results in cluster formation leading to the isolation of a rare bicapped tetrahedral [Cu6I2] cluster that is stabilised by two conformationally constrained polynucleating ligands.
doi:10.1039/c6dt04703c
pmid:28133681
fatcat:zsll33q24nhaxjixibxyzztnii