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Hydrothermal Synthesis of New Compounds with the Pyrochlore Structure and Its Application to Nitric Oxide Abatement
Journal of the Ceramic Society of Japan
Several new compounds with a pyrochlore-type crystal structure have been synthesized by a low-tempera ture hydrothermal process under N2 atmosphere using a mixture of nitrate salts. The chemical compositions of the new pyrochlores are represented as (a) Y2Sn1.8Cr0.2O7, . The Ba and Ca-containing pyrochlores exhibited excellent spherical morphology with a pure pyrochlore phase structure and were composed of nanometer-sized particles. A-and B-site doped pyrochlores maintained a fully ordereddoi:10.2109/jcersj.110.963 fatcat:66dqe565cfcltfxbkibjlc7e6i