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A review devoted to the theory of excitonic quasimolecules (Biexcitons) (formed of spatially separated electrons and holes) in a nanosystems that consists of semiconductor and dielectric quantum dots synthesized in a dielectric matrix. It is shown that exciton quasimolecules formation is of the threshold character and possible in nanosystems, in with the spacing between the quantum dots surfaces is larger than a certain critical spacing. It was found that the binding energy of singlet grounddoi:10.4172/2329-6798.1000188 fatcat:twrxugsssnfv3h7rattzgbnaje