A copy of this work was available on the public web and has been preserved in the Wayback Machine. The capture dates from 2022; you can also visit the original URL.
The file type is application/pdf.
Triple-decker complexes incorporating three distinct deck architectures
2022
Preserved Fulltext
The reactivity of the dilithioplumbole ([Li$_{2}$(thf)$_{2}$(μ,η$^{5}$-L$^{Pb}$)], L$^{Pb}$ = 1,4-bis-tert-butyl-dimethylsilyl-2,3-bis-phenyl-plumbolyl) towards the reactive pnictogen precursors P$_{4}$, pentaphosphaferrocene, and pentaarsaferrocene ([Cp*Fe(η$^{5}$-E$_{5}$)] (Cp* = η$^{5}$-C$_{5}$Me$_{5}$, E = P, As)) is reported. The reaction with P$_{4}$ afforded a phospholyl lithium complex, via lead-phosphorus exchange, while the reactions with [Cp*Fe(η$^{5}$-E$_{5}$)] yielded the first
doi:10.5445/ir/1000142387
fatcat:h7dclyatlbgelbjhyb2h3pfr5e