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Polyoxometalates have been investigated for use as high-capacity cathode materials in lithium batteries due to their high capacity, cycle stability, and recoverability of crystal structure during charge-discharge. However, POMs have weak points when used as the cathode electrode for lithium batteries: low electronic conductivity and high surface reactivity. In this study, we used a conducting polymer, polypyrrole (PP), to coat the surface of nano-sized polyoxovanadate K 9 PV 14 O 32 (KPV) anddoi:10.1149/2.0341903jes fatcat:ffipilyzhbbkvc7i55s7z77bmm