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Rotational spectra and equilibrium structures of H2SiS and Si2S
Journal of Chemical Physics
The rotational spectra of two small silicon sulfides, silanethione H 2 SiS and the disilicon sulfide ring Si 2 S, have been detected in the centimeter band by Fourier transform microwave spectroscopy of a molecular beam; lines of H 2 SiS were also observed in the millimeter band up to 377 GHz in a glow discharge. Precise rotational and centrifugal distortionconstants have been determined for the normal and a number of the more abundant rare isotopic species of both closed-shell molecules.doi:10.1063/1.3510732 pmid:21261352 fatcat:djcpgukljvgfhf4cyl45gi76cy