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Synthesis-Controlled Polymorphism, Magnetic and Electrochemical Properties of Li3Co2SbO6
[post]
2019
unpublished
<div>Li3Co2SbO6 is found to adopt two highly distinct structural forms: a hexagonal layered O3- LiCoO2 type phase with "honeycomb" 2:1 ordering of Co and Sb; and an orthorhombic superstructure of rock-salt type, isostructural with Li3Co2TaO6 but with the addition of significant Li/Co ordering. Pure samples of both phase scan be obtained by conventional solid-state synthesis from the same precursors, Li3SbO4 and CoO, by controlling particle size and reaction time. Both phases show relatively
doi:10.26434/chemrxiv.8246966.v2
fatcat:2m24ziz4orb7pgi7r374qc5l7m