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Eine silberhaltige Phase eines Oxoruthenats: Ag0,4 (Na2,3Ca4,3RuO8 / A Silver Containing Phase of an Oxoruthenate: Ag0,4Na2,3Ca4,3RuO8

S. Frenzen, Hk. Müller-Buschbaum
1996 Zeitschrift für Naturforschung. B, A journal of chemical sciences  

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Single crystals of Ag0.4Na2.3Ca4.3RuO8 have been prepared by heating Na2O2, CaO and ruthenium in closed silver tubes. Silver took part in the reaction. The crystal structure was investigated by X-ray techniques. AgO4Na2.3Ca4.3RuO8 crystallizes with orthorhombic symmetry, space group D192h-Cmmm ; a = 9.255(1), b = 6.683(1), c = 6.696(3) Å , Z = 2. It shows relations to the sodium chloride structure. A statistical distribution of Ag+ and Na+ can be separated in micro space by splitting one oxygen
more » ... position to give a dumb-bell like O-Ag-O and an octahedral NaO6 coordination.
doi:10.1515/znb-1996-0408 fatcat:lylg3nu3xjh27g5kvklbu6ygsy
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S. Frenzen, Hk. Müller-Buschbaum. "Eine silberhaltige Phase eines Oxoruthenats: Ag0,4 (Na2,3Ca4,3RuO8 / A Silver Containing Phase of an Oxoruthenate: Ag0,4Na2,3Ca4,3RuO8." Zeitschrift für Naturforschung. B, A journal of chemical sciences 51.4 (1996) 485-488