Crystal structure of trans-dichloro-1,3-propanediamine-bis[(2-methoxyethyl) diphenylphosphine]ruthenium(II), RuCl2(C3H10N2)(C15H17OP)2

I. Warad, S. Al-Resayes, K. Eichele
2006 Zeitschrift für Kristallographie - New Crystal Structures  
C 33 H 44 Cl 2 N 2 O 2 P 2 Ru, monoclinic, P12 1 /c1 (no. 14), a = 13.278 (1) Source of material All the reactions were performed using Schlenk-type flask under argon and standard high vacuum-line techniques. Solvents were of analytical grade and distilled under argon. The title compound was synthesized by treating RuCl 2(h 2 -Ph2PCH2CH2OCH3)2 complex with slightly excess 1.3-propanediamine ligand in dichloromethane as described previously [1] . The crystals were grown by slow diffusion of
more » ... w diffusion of diethyl ether into a solution of the complex in dichloromethane. They were re-crystallized from these two solutions. The desired complex was characterized by NMR, IR, and FAB-mass spectroscopy in addition to the elemental analysis [1, 2] .
doi:10.1524/ncrs.2006.0072 fatcat:ahpvter5u5fjxlul5gvw7l7zbm