Synthesis and Spectroscopic Studies of New Palladium(II) Complexes of N-hydroxymethyl Saccharin (Sac-CH2OH) and Amines or Diaminas Ligands

Ahmed S. Al-Janabi, Adnan A. Al-Dulaimi, Hayfa M. Gergees, Mohammed H. Saleh
2019 Oriental Journal of Chemistry  
Treatment of the chelated palladium(II) complex, trans-[Pd(K 2 -Sac-CH 2 O) 2 ].2H 2 O with one mole equivalent of the diammines (L-L), L-L = 2,2'-bipyridine (bipy), ethylene diamine (en), 1,10-phenanthroline (phen), or N,N-dimethyl ethylene diammine (dmen) in EtOH solvent afforded mixed ligand complexes of the type [Pd(K 1 -Sac-CH 2 O) 2 (L-L)] in 82-93% yield. While treatment of trans-[Pd(K 2 -Sac-CH 2 O) 2 ] .2H 2 O with two mole equivalents of the monoamines (L), L=pyridine (py),
more » ... idine (3-mpy) or 3-aminopyridine (3-apy) in EtOH solvent gave trans-[Pd(K 1 -Sac-CH 2 O) 2 (L) 2 ] complexes in 86-89% yield The prepared complexes were characterized by elemental CHN analysis, .conductivity measurements, infrared and 1 H nmr spectra.
doi:10.13005/ojc/350121 fatcat:3v3hgz6wfjewtia2ldr7jlt6c4