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Electrospray Mass Spectrometric Detection of Neutral Metal Bipyridine Complexes Using Sodium Ions and Its Application in the Analysis of a Photochemical Ligand Substitution Reaction
1998
Analytical Sciences
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Sodium ions can be used as efficient chemical ionization agents in electrospray mass spectrometry of a wide variety of neutral metal bipyridine complexes. This ionization method was successfully permitted the identification of a neutral metal complex generated during the photochemical ligand substitution reaction: [Re(bpy)(CO)3{P(OEt)3}] + +Cl -® Re(bpy)(CO)2{P(OEt)3}Cl+CO by sodium adduct formation to produce an electrospray-active species [Re(bpy)(CO)2{P(OEt)3}Cl+Na] + .
doi:10.2116/analsci.14.287
fatcat:4yinfhnktfhqvaphhs4vxmjqp4