With the economic growth and increasing urbanization in the last three decades, the air quality over China has continuously degraded, which poses a great threat to human health. The concentration of fine particulate matter (PM 2.5 ) directly affects the mortality of people living in the polluted areas where air quality is poor. The Beijing-Tianjin-Hebei (BTH) region, one of the well organized urban regions in northern China, has suffered with poor air quality and atmospheric pollution due to

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... ent growth of the industrial sector and vehicle emissions. In the present study, we used the back propagation neural network model approach to estimate the spatial distribution of PM 2.5 concentration in the BTH region for the period January 2014-December 2016, combining the satellite-derived aerosol optical depth (S-DAOD) and meteorological data. The results were validated using the ground PM 2.5 data. The general method including all PM 2.5 training data and 10-fold cross-method have been used for validation for PM 2.5 estimation (R 2 = 0.68, RMSE = 20.99 for general validation; R 2 = 0.54, RMSE = 24.13 for cross-method validation). The study provides a new approach to monitoring the distribution of PM 2.5 concentration. The results discussed in the present paper will be of great help to government agencies in developing and implementing environmental conservation policy.