This report brings new facts and achievements on the cine-and tele-substitutions reactions published in the last fifteen years. The reactions occurred primarily in such systems as nitroarenes, metal homoarene complexes, and five-or six-membered heteroarenes. Sometimes similar reactions were also observed in other systems, including non-aromatic. cine-and tele-Substitution reactions are presented here independently of their mechanisms. H Y b a n cine tele