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Symmetry-breaking charge transfer reaction of 9,9'-bianthracene is driven exclusively by the rotational fluctuation of solvents, not including the inertial component in the solvation dynamics. Torsional motion and bond shortening during the reaction were observed.doi:10.1051/epjconf/201920509008 fatcat:4svkgwhg7vdxdaeoyi5xygetsi