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Electron and excitation transfer in hetero-supramolecular assemblies and at moleculenanoparticle interfaces
2003
Pure and Applied Chemistry
Preserved Fulltext
Encapsulation of chromophores within Cram-type hemicarcerands allowed the investigation of fundamental photophysical phenomena, such as long-range triplet energy transfer, electron transfer, and the remote heavy atom effect. Furthermore, novel water-soluble hemicarcerands are being used to develop unique hybrid materials composed of semiconductor nanoparticles and host–guest assemblies. Photoinduced charge injection from the "incarcerated" guest into the conduction band of the semiconductor has been demonstrated.
doi:10.1351/pac200375081061
fatcat:5m3fcdhhinhpfoabjiwrc7hssa