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AbstractTrialkylsilanols were reported to modify and also to improve the catalytic performance in ethylene polymerization when added to zirconocene/methylaluminoxane (MAO) systems. In order to obtain more information about the chemistry involved, a new stable catalytic precursor was investigated in this work. The precursor bis(h5-cyclopentadienyl)bistriphenylsilanolatozirconium(IV) [ZrCpdoi:10.1515/epoly.2001.1.1.66 fatcat:ig5xvo7cdzaslf6is2hqtlh5lu