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This study focusses on the description of the nucleation process observed during the ozone reaction of the biogenic monoterpene α-pinene in smog chambers. Therefore, a detailed aerosol dynamics model (UHMA) was extended by a tropospheric chemistry module and a detailed description of the first steps of organic nucleation. We assume 5 secondary ozonides to act as nucleation initiating molecules, which are subsequently activated by reactions with organic peroxy radicals (RO 2 ). With this set-updoi:10.5194/acpd-7-3901-2007 fatcat:hr4qfkcqonfaddwmyhvoo2ndt4