A copy of this work was available on the public web and has been preserved in the Wayback Machine. The capture dates from 2018; you can also visit the original URL.
The file type is application/pdf.
Metallkomplexe mit Tetrapyrrol-Liganden, XVIII* Osmiumkomplexe des meso-Tetra(p-tolyl)porphyrins / Metal Complexes with Tetrapyrrole Ligands, XVIII* Osmium Complexes of meso-Tetra(p-tolyl)porphyrin
1977
Zeitschrift für Naturforschung. B, A journal of chemical sciences
Preserved Fulltext
The preparation and spectroscopic characterization of osmium tetra(p-tolyl)porphyrin complexes, Os(TTP)LL′ (2c-21; L or L′ = CO, N2, EtOH, THF, Py, PPh3, P(OMe)3, methoxide or oxide) are described. 2c-21 are compared with the analogous octaethylporphyrin complexes, 1c-11. In 2c-21, the porphyrin ligand is a stronger π-acceptor than in 1c-11. The π-acceptor capacity of the porphyrin ligand renders the dinitrogenosmium(II) porphyrins 1j or 2j less stable than the dinitrogenpentammineosmium(II) cation.
doi:10.1515/znb-1977-1215
fatcat:6xbigvibs5hztp4p5oleiho35i