Crystal structure of tetraaqua-(1,10-phenanthroline-N,N')manganese(II) sulfate dihydrate, [Mn(H2O)4(phen)]SO4 · 2H2O

Y.-Q. Zheng, J.-L. Lin
2001 Zeitschrift für Kristallographie - New Crystal Structures  
C12H20M11N2C) 1 oS, orthorhombic, Pbca (No. 61), a = 8.877(2)Ä, b = 18.509(1)Ä, c = 22.087(2)Ä, V= 3629.0 Ä 3 , Z= 8, R %l (F) = 0.034, wRretfF 2 ) = 0.088, T= 293 K. Source of material Yellow crystals of the title compound were grown by the reaction of MnS0 4 · H 2 0 (0.100 g, 0.592 mmol), phenanthroline monohydrate (0.117 g, 0.592 mmol) and suberic acid (0.103 g, 0.592 mmol) dissolved in 25 ml CH3CH2OH/H2O (1:1 v/v), followed by slow evaporation of the solvent at room temperature. Repeated
more » ... rature. Repeated experiments showed that the presence of suberic acid is essential for the crystal growth.
doi:10.1524/ncrs.2001.216.14.375 fatcat:btz224375fgm5jvusecjbh6tfi