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Recebido em 20/8/02; aceito em 21/2/03 REGIO-AND STEREOCHEMICAL ASPECTS OF THE ASYMMETRIC MICHAEL ADDITION USING CHIRAL IMINES BEARING A RESIDENT STEREOGENIC CENTER. The asymmetric Michael addition reactions using chiral imines, under neutral conditions (deracemizing alkylation process), constitute one of the main methods for the stereocontrolled elaboration of quaternary carbon centers. This protocol is based on the conjugate addition of secondary chiral enamines to electron-deficient alkenes.doi:10.1590/s0100-40422003000500016 fatcat:65wjjewlobcunlozcncrko3dem