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Reticular chemistry concerns the linking of molecular building blocks into predetermined structures using strong bonds. We have been working on creating and developing the conceptual and practical basis of this new area of research. As a result, new classes of crystalline porous materials have been designed and synthesized: metal-organic frameworks, zeolitic imidazolate frameworks, and covalent organic frameworks. Crystals of this type have exceptional surface areas (2,000-6,000 m 2 /g) anddoi:10.1557/mrs2009.180 fatcat:kyfr7n7e2vhgrcheysbn5g3gzq