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Chemical Effect on theD522:D322Branching Ratio of the5dPhotoionization of Pb
1985
Physical Review Letters
Preserved Fulltext
Significant intershell interaction effects are observed in the 5d branching ratio of the heavy nontransition metal Pb. Atomic calculations reveal their atomic character, but a distinct influence of the chemical environment on the branching-ratio's energy dependence is reported for the compounds PbI2 and Pb02.
doi:10.1103/physrevlett.55.2133
pmid:10032057
fatcat:5haexyg3azakpja5ffl2wqj7xm