Synthesis, Structure and Electrochemical Characterization of the Isopolytungstate (W4O16) held by MnII Anchors within a Superlacunary Crown Heteropolyanion {P8W48}

Masooma Ibrahim, Israel Martyr Mbomekalle, Pedro De Oliveira, George E. Kostakis, Christopher Anson
2019 Dalton Transactions  
An isopolyanion within heteropolyanion assembly [(P8W48O184)(W4O16)K10Li4Mn10Na(H2O)50Cl2]15- (Mn10W4-P8W48) has been synthesized by the reaction of the cyclic superlacunary anion [H7P8W48O184]33− and Mn(ClO4)2.6H2O in I M LiCl soultion medium at pH 8....
doi:10.1039/c9dt02478f fatcat:rvzal4mmffglzdq4ftbm32kjti