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The thermodynamic quantities (log K , AH, &Y, and ACp) associated with the interactions of protons and metal ions with ligands in aqueous solutions are strongly influenced by the structure and properties of water. These quantities, especially AS and AH, reflect the decrease in hydrogen bonding in water as temperature increases. The magnitude and the sign of AS and AH for proton interaction with amino acid and nucleotide anions are indicative of the interaction of charged species with water, thedoi:10.1351/pac199567040543 fatcat:rxtktk3oqndsnnqpturjppzgty