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Our recent synthetic studies In polynuclear phthalocyanine chemistry are reviewed. The electronic coupling which occurs between the various phthalocyanine units are probed by electronic absorption and emission spectroscopy. Many of the complexes are effective as oxygen reduction electrocatalysts and these studies, carried out with the catalysts as monolayers on ordinary pyrolytic graphite surfaces, are discussed. Under certain circumstances, the cobalt(II) phthalocyanine species willdoi:10.1351/pac198658111467 fatcat:xybhionzz5dizhi5hrpv2o4ee4