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An elementary chemical reaction proceeds through two distinct conical intersections. Benzhydryl radicals are formed with a delay of 80 fs, cations after 125 fs. The optical signal increases more slowly due to planarization and solvation. 05042-p.3doi:10.1051/epjconf/20134105042 fatcat:i7z32irijbdl7au3vlkgygutwa