A copy of this work was available on the public web and has been preserved in the Wayback Machine. The capture dates from 2017; you can also visit the original URL.
The file type is application/pdf
.
Field-induced internal Fe and Ln spin reorientation in butterfly{Fe3LnO2}(Ln=Dy and Gd) single-molecule magnets
2013
Physical Review B
The intramolecular exchange interactions within the single-molecule magnet (SMM) "butterfly" molecule [Fe 3 Ln(μ 3 -O) 2 (CCl 3 COO) 8 (H 2 O)(THF) 3 ], where Ln(III) represents a lanthanide cation, are determined in a combined experimental [x-ray magnetic circular dichroism (XMCD) and vibrating sample magnetometer (VSM)] and theoretical work. Compounds with Ln = Gd and Dy, which represent extreme cases where the rare earth presents single-ion isotropic and uniaxial anisotropy, on one hand, and
doi:10.1103/physrevb.87.184403
fatcat:ssaq7pfcqbezdojwrry675wlma