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The electronic structure of the VO film grown on Ag(100) has been studied by photoelectron spectroscopy (PES) utilizing synchrotron radiation. The Ag(100) surface covered by the VO film formed by V deposition in O2 at 3.7×10 −9 Torr and subsequent annealing at 450 • C gave a (1×1) LEED pattern. In the PES spectra for the (1×1) VO film, the conduction band mostly composed of V 3d-components was observed at 0-2.5 eV. The valence band mostly composed of O 2p-components was formed overlapping withdoi:10.1380/ejssnt.2018.236 fatcat:236ki3x3qvgiho2m23onbxmdlm