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Syntheses, Structures and Photoluminescent Properties of Two New Pb(II) and Cd(II) Coordination Polymers Constructed from 1,10-Phenanthroline-derived and 1,4-Naphthalenedicarboxylate Ligands
Zeitschrift für Naturforschung. B, A journal of chemical sciences
Two new related coordination polymers, namely, [Pb(L)(1,4-ndc)] · 0.5H2O (1) and [Cd(L)(1,4- ndc)] · 0.5H2O (2), where L = 2-(3-fluorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline and 1,4- ndc = 1,4-naphthalenedicarboxylate, were synthesized under hydrothermal conditions. Crystal data for 1: C62H36F2N8O9Pb2, monoclinic space group C2/c, a = 15.874(3), b = 19.982(4), c = 16.045(3) Å, β = 94.26(3), V = 5075.3(18) Å3, Z = 4. Crystal data for 2: C62H36Cd2F2N8O9, monoclinic space group P21/n, a =doi:10.1515/znb-2012-0105 fatcat:6y4hv5eue5a5lm6kavjuhltzyu