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The interdiffusion coefficient and the ratio of the intrinsic diffusivities with respect to the mole fixed frame of reference in Ag-Cd alloys have been determined by taking the volume change effects into account. The interdiffusivities obtained in this work are in good agreement with those obtained by previous workers. The ratio of the intrinsic diffusivities has been determined to be 1.50 at 8.6 at% Cd for Ag-15 at %Cd-Ag diffusion couple and 1.54 at 12.6 at% Cd for Ag-25 at% Cd-Ag diffusiondoi:10.2320/matertrans1960.28.457 fatcat:lcq46ub7zvb5xdnmmlp7jtjmhi