Interstitial boron in MnFe(P,As) giant-magnetocaloric alloy

Z.Q. Ou, L. Caron, N.H. Dung, L. Zhang, E. Brück
2012 Results in Physics  
Keywords: Magnetocaloric effect Fe2P-based interstitial element a b s t r a c t The influences of boron addition on the phase formation, Curie temperature and magnetic entropy change of the Mn 0.95 Fe 1.05 P 0.5 As 0.5 compound have been investigated. All the samples crystallize in the hexagonal Fe 2 P-type structure and boron enters into the basal plane as an interstitial element. The Curie temperatures can be adjusted by varying the boron content. Strong field-induced itinerant-electron
more » ... agnetic transitions with small hysteresis are observed. With boron addition in small amounts the giant-magnetocaloric effects are slightly enhanced. This study provides a novel route to tune optimal working temperatures and improve magnetic properties and magnetocaloric effect.
doi:10.1016/j.rinp.2012.09.005 fatcat:qiuq4d7cofdnpfmji4volfcsna