Chemical and isotopic fingerprinting of small ungauged watershed: How far the hydrological functioning can be understood?

Emmanuelle Petelet-Giraud, Jean-Marc Luck, Dalila Ben Othman, Christian Joseph, Philippe Négrel
2016 Comptes rendus Geoscience  
This study presents the ability of major/trace elements together with strontium isotopes to trace water origins at small scale at the outlet of a small watershed (Peyne, Hé rault, France). Two small sub-basins draining distinct lithologies in their headwater (Plio-Villafranchian conglomerate versus Triassic gypsum-rich marls and dolomites) and the Miocene formations downstream are investigated. The Ca/Na vs. Mg/Na ratios and Ca/Sr vs. 87 Sr/ 86 Sr ratios allow the different facies that imprint
more » ... he water signature to be identified, according to the hydrological conditions (low/high flows). Moreover, Sr isotopes evidence the two distinct Miocene facies, the sandy marls and the marine carbonates. The variation of the signature at the outlet of the basin allows identifying the main contributing compartments according to the hydrological conditions. This approach, based on a limited number of samples, highlights the potential of geochemical and isotopic tracers to define the contributing compartments to the runoff at the outlet of a basin. It thus could be considered as a potential alternative way to classical hydrological monitoring to delineate the main contributing areas during floods, especially in small ungauged river basins, where most of the devastating flash floods are recorded. ß 2016 Acadé mie des sciences. Published by Elsevier Masson SAS. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/ 4.0/).
doi:10.1016/j.crte.2016.03.001 fatcat:ybeyasaejzgbfflnz7nxejiwqe