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Macromolecular Complex Viscosity from Space-Filling Equilibrium Structure
2022
Physics of Fluids
Macromolecular theory for the rheology of polymer liquids usually proceeds from a scale much larger than chemical bonding. For instance, a bead in a general rigid bead-rod theory can represent a length of polymer. This is why we sculpt the shape of the macromolecule with a rigid bead-rod model. From the macromolecular hydrodynamics that follows, we then discover that the rheology of polymer liquids depends on the macromolecular moments of inertia. In this paper, we use this discovery to arrive
doi:10.1063/5.0116558
fatcat:slsicqub5jb4bbl6qiircxfpgq