Unusual Influence of the Temperature on the Standard Rate Constants of Charge Transfer for the Eu(III)/Eu(II) Redox Couple in Chloride-Bromide Melts

Sergey A. Kuznetsov, Marcelle Gaune-Escard
2007 Zeitschrift fur Naturforschung A-A Journal of Physical Sciences  
The influence of bromide ions and temperature on the standard rate constants of the Eu(III)/Eu(II) redox reaction was determined. Cyclic voltammetry was used for the calculation of the kinetic parameters. It was shown that in NaCl-KCl (equimolar mixture)-NaBr (15 wt%)-EuCl
doi:10.1515/zna-2007-7-815 fatcat:ewwuooa635g4pezpmjcvah6ruu