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Dynamics and Rheology of a Supercooled Polymer Melt
2000
Progress of Theoretical Physics Supplement
Molecular dynamics simulations are performed for a polymer melt composed of short chains in quiescent and sheared conditions in supercooled states. In quiescent states, while the self chain motions are excellently described by the Rouse model, the stress relaxation function G(t) exhibits a stretched exponential decay in a relatively early stage and ultimately follows the Rouse function. Transient stress evolution after application of shear obeys the linear growth Ê t 0 dt G(t ) for strain less
doi:10.1143/ptps.138.336
fatcat:oxqr5a6v2rcs5kxts2fadop2wy