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In the solvated title salt, [RhCl2(C5H5N)4]Cl·4CH3OH, the RhIIIatom lies on a special position of 2.22 site symmetry. Consequently, the cationic complex has molecularD2symmetry with atransdisposition for two equivalent Cl−and four equivalent pyridine ligands. The Rh—Cl and Rh—N bond lengths are 2.3452 (7) and 2.064 (2) Å, respectively. The planes of the coordinating pyridine ligands are tilted synchronously, with a dihedral angle of 40.76 (9)° between the least-squares pyridine plane and thedoi:10.1107/s2414314618014827 fatcat:zfgmwzxdgfbyxllzy4nmen2gri