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The kinetics of the oxidation of [Co II (ADA)(M)(H 2 O) 2 ] 2-(ADA = N-(2-acetamido)iminodiacetic and M = Malonate) by periodate in acetate medium have been investigated spectrophotometrically at 580 nm under pseudo first order condition by taking large excess of oxidant (IO 4-) over the 15.0-35.0C range at pH = 4.99 and I = 0.50 M. The kinetics in acetate medium obeyed the rate law: d[Co III ]/dt = (k 2 + k 3 [CH 3 CO 2-])[Co II (ADA)(M)(H 2 O) 2 ] 2-[IO 4-]. The initial cobalt(III) productsfatcat:6wdlh6cofrhwzn3ngqy3udjpxm