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AbstractConsidered are blends of the flexible coil-shaped poly(vinyl chloride) (PVC) and rigid coil-shaped polymers, poly(norbornene ester)s, characterized by strong rotational constraints. The unexpected finding is that the stepwise increase of the specific heat at the glass transitiondoi:10.1515/epoly.2001.1.1.41 fatcat:se662uao3ja4fo2m2r5d25ntfu