Crystal structure of trans-dichloro-bis[(E)-2-(1-methoxy-imidazol-2-yl)-2-oxoacetaldehyde O-methyl oxime]palladium(II), PdCl2(C7H9N3O3)2

Gerhard Laus, Klaus Wurst, Herwig Schottenberger
2012 Zeitschrift für Kristallographie - New Crystal Structures  
C 14 H 18 Cl 2 N 6 O 6 Pd, triclinic, P1 (no. 2), a =7.4741 (5) Source of material Am ixture of PdCl 2 and (E)-2-(1-methoxyimidazol-2-yl)-2oxoacetaldehyde O-methyl oxime [1] (2 equiv.) in MeOH was stirred for 4hatroom temperature. The product precipitated and was filtered off and washed with MeOH and Et 2 O. Yellow single crystals were obtained by slow evaporation of as olution in CH 3 CN (yield 71 %, m.p. 195°C).
doi:10.1524/ncrs.2012.0008 fatcat:wwn6ykursjeb5hv4e773u5crju