Untersuchungen über Substituenten-Einflüsse auf die reduktive Eliminierung des Biphenyl-Systems aus cis-Bis(aryl)bis(triphenylphosphan)platin(II)-Verbindungen/ Influence of Substituents on the Reductive Elimination of the Biphenyl-System from cis-Bis(aryl)bis(triphenylphosphane)platinum(II) Compounds

Ulrich Bayer, Hans Albert Brune
1983 Zeitschrift für Naturforschung. B, A journal of chemical sciences  
Compounds cis-[Pt(PPh3)2(3-X-C6H4)2] [X = F, Cl, CF3, CH3O, (CH3)2N] and cis- [Pt(PPh3)2(3-X-C6H4)(Y-C6H4)] [X = F / Y = H, 4-F, 4-CF3, 4-CH3O; X = Cl/Y = 4-F; X = CF3 /Y = 4-F; X = CH3O/Y = 4-F] have been synthesized and studied thermally with respect to the reductive elimination of disubstituted biphenyls. Activation parameters ⊿H≠ and ⊿S≠ are reported and discussed.
doi:10.1515/znb-1983-0517 fatcat:sgmh3n5wbvdhjdgcb2uvbh6w7y