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Tetramethyldistibane reacts with equimolar amounts of di-p-tolylditelluride to yield quantitatively p-tolyltellurodimethylstibane, the first molecule with a Te-Sb bond. The compound has been characterised by elemental analysis and by NMR and mass spectra.doi:10.1515/znb-1983-1026 fatcat:oupb67eb4nb4nj5lghuej3f7re