Pair Correlation Functions in Nematics: Free-Energy Functional and Isotropic-Nematic Transition
Pankaj Mishra, Yashwant Singh
2006
Physical Review Letters
We develop a free energy functional for an inhomogeneous system that contains both symmetry conserved and symmetry broken parts of the direct pair correlation function. These correlation functions are found by solving the Ornstein- Zernike equation with the Percus-Yevick closure relation. The method developed here gives the pair correlation functions in the ordered phase with features that agree well with the results found by computer simulations. The theory predicts accurately the
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... atic transition in a system of anisotropic molecules and can easily be extended to study other ordered phases such as smectics and crystalline solids.
doi:10.1103/physrevlett.97.177801
pmid:17155507
fatcat:oqb5ixmo65cfhedfsn4xfewuoa