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Stereoselective Suzuki Coupling Reaction of an α-Bromo-α-fluoro-β-lactam
2014
Synlett : Accounts and Rapid Communications in Synthetic Organic Chemistry
A new strategy has been developed for the synthesis of α-aryl-α-fluoro-β-lactams via the Suzuki cross-coupling of α-bromoα-fluoro-β-lactam with a range of different aryl-(9-BBN) reagents. This method provides facile access to multisubstituted α-fluoro-β-lactams in a diastereoselective manner. The synthetic utility of α-bromo-α-fluoroβ-lactam has been demonstrated by the arylation of α-bromo-α-fluoroβ-lactam.
doi:10.1055/s-0034-1379637
fatcat:ikhxdgkl6vekbj2gt45fxov6vu