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Stereoselective synthesis of carbohydrate-based fused bicyclic delta-lactones
2003
Journal of the Brazilian Chemical Society
Relata-se no presente trabalho a síntese de δ-lactonas quirais derivadas de carboidratos, por meio de reações de ciclização radicalar regio-e estereosseletivas. A configuração do novo centro estereogênico depende da estrutura do carboidrato. We describe in the present work the synthesis of carbohydrate-based chiral δ-lactones by regioand stereoselective radical cyclization reactions. The configuration of the newly stereogenic center was found to depend on the structure of the carbohydrate moiety.
doi:10.1590/s0103-50532003000300017
fatcat:o3lotuqtknfefcebk35d36rbie