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Three emitting copolyfluorenes, based on 2,7-(9,9-dihexyl)fluorene and different aryl groups were blended with a polyimide 6FDA–6FpDA to make gas separation membranes. Their intrinsic fluorescence correlates with their permselectivity.doi:10.1039/c5ra03809j fatcat:bdthnh2u2zf6pn366b6ix5ogpe